Free Practice Test: AP Chemistry

Last updated: August 16, 2026

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AP exams let you earn college credit, test out of an intro-level class, or both, while showing college admissions officers you can handle rigorous coursework. Most colleges and universities in the US recognize AP credit for a strong score.
AP Chemistry is the equivalent of a full year of introductory college chemistry, and it has a reputation for being one of the more demanding AP science exams: both because of the conceptual depth and because it requires real quantitative fluency, not just memorization. A solid foundation in algebra and basic lab skills from an introductory chemistry course goes a long way here.

Fast Chemistry Study Guide

The AP Chemistry exam runs about 3 hours and 15 minutes. Section I is 60 multiple-choice questions in 90 minutes; a four-function, scientific, or graphing calculator is not allowed for this section. Section II is seven free-response questions in 105 minutes: three long-form questions and four short-answer questions, and a calculator is allowed for the entire free-response section. You'll also be given a periodic table and standard reference tables (equations and constants) for both sections. Multiple-choice and free-response sections are weighted equally toward your final score of 1 to 5. Double-check current timing and the exact calculator policy against the AP Course and Exam Description, since specifics are occasionally revised.

Atomic Structure, Bonding, and Intermolecular Forces (30–40% combined)

The first three units build your model of matter from the atom up. Atomic Structure covers electron configuration, periodic trends (atomic radius, ionization energy, electronegativity), and how mass spectrometry data is interpreted. Molecular and Ionic Bonding covers Lewis structures, VSEPR molecular geometry, and the differences between ionic, covalent, and metallic bonding. Intermolecular Forces covers London dispersion forces, dipole-dipole interactions, and hydrogen bonding, and how those forces explain macroscopic properties like boiling point, viscosity, and solubility.

Chemical Reactions and Kinetics (18–24% combined)

Chemical Reactions covers stoichiometry, reaction types (synthesis, decomposition, single/double replacement, combustion), and net ionic equations. Kinetics covers reaction rates, rate laws, and how to determine reaction order from experimental data. A recurring free-response format is a data table you have to use to derive a rate law yourself. Collision theory and the effect of catalysts on activation energy round out this pair of units.

Thermodynamics and Equilibrium (24–30% combined)

Thermodynamics covers enthalpy, entropy, and Gibbs free energy, and how to predict whether a reaction is spontaneous. Equilibrium covers the equilibrium constant (Kc and Kp), Le Chatelier's Principle, and ICE tables for calculating equilibrium concentrations. This is one of the most quantitatively demanding stretches of the course, and it's tested extensively in the free-response section, where you'll often need to set up and solve a multi-step calculation rather than just recall a definition.

Acids and Bases (11–15%)

Covers the Brønsted-Lowry definition of acids and bases, pH and pOH calculations, weak acid/base equilibria (Ka and Kb), buffer solutions and the Henderson-Hasselbalch equation, and titration curves. Being able to read a titration curve and identify the equivalence point, half-equivalence point, and buffer region is a near-guaranteed free-response skill on this exam.

Electrochemistry

The final major topic covers oxidation-reduction (redox) reactions, balancing redox equations, and galvanic (voltaic) cells versus electrolytic cells. You'll need to calculate standard cell potential from standard reduction potentials and connect electrochemistry back to thermodynamics through the relationship between cell potential, Gibbs free energy, and the equilibrium constant.

Chemistry Free Practice Test

So, are you ready to test the waters? Take this practice quiz and judge your preparation level before diving into deeper study. AP test questions cover a mix of multiple-choice questions and free-response questions. The following are original sample questions, written by Powerhouse Prep, in the style of the types of questions that may appear on the exam.

Question 1: Which of the following correctly ranks the intermolecular forces present in liquid water from strongest to weakest contributor to its unusually high boiling point?

  1. London dispersion forces > dipole-dipole forces > hydrogen bonding
  2. Hydrogen bonding > dipole-dipole forces > London dispersion forces
  3. Dipole-dipole forces > hydrogen bonding > London dispersion forces
  4. All intermolecular forces contribute equally in water

Correct Answer: B. Hydrogen bonding > dipole-dipole forces > London dispersion forces

Explanation: Water's O-H bonds are highly polar, and because hydrogen is bonded directly to a small, highly electronegative atom (oxygen), water molecules form unusually strong hydrogen bonds, a special, stronger case of dipole-dipole attraction. Hydrogen bonding is the dominant force explaining water's surprisingly high boiling point relative to molecules of similar molar mass that can't hydrogen bond, followed by general dipole-dipole attraction, with the always-present but comparatively weak London dispersion forces contributing least.


Question 2: A reaction is found to be second order overall and first order with respect to each of its two reactants, A and B. If the concentration of A is doubled while B is held constant, what happens to the reaction rate?

  1. The rate stays the same
  2. The rate doubles
  3. The rate quadruples
  4. The rate is cut in half

Correct Answer: B. The rate doubles

Explanation: Since the reaction is first order with respect to A, the rate law includes [A]^1. Doubling [A] while holding [B] constant doubles the rate, since rate is directly proportional to [A] raised to the first power. The rate would only quadruple if the reaction were second order with respect to A specifically (rate proportional to [A]^2), which isn't the case here.


Question 3: According to Le Chatelier's Principle, if the pressure on a gas-phase equilibrium system is increased by decreasing the container volume, the equilibrium will shift toward which side of the reaction?

  1. The side with more moles of gas
  2. The side with fewer moles of gas
  3. Equilibrium will not shift regardless of the number of moles of gas on each side
  4. The reaction will stop entirely

Correct Answer: B. The side with fewer moles of gas

Explanation: Increasing pressure by decreasing volume stresses the system, and per Le Chatelier's Principle, the equilibrium shifts to relieve that stress by favoring the side with fewer moles of gas, since that reduces the total number of gas particles and partially offsets the pressure increase. If both sides have equal moles of gas, a pressure change has no effect on the equilibrium position.


Question 4: A buffer solution is prepared using acetic acid (CH3COOH, a weak acid) and sodium acetate (CH3COONa). What is the primary function of this buffer?

  1. It permanently neutralizes all acids and bases added to it
  2. It resists significant changes in pH when small amounts of acid or base are added
  3. It increases the pH of the solution continuously over time
  4. It converts the weak acid into a strong acid

Correct Answer: B. It resists significant changes in pH when small amounts of acid or base are added

Explanation: A buffer resists significant pH changes when small amounts of acid or base are added, because it contains both a weak acid (acetic acid) that can neutralize added base, and its conjugate base (acetate ion) that can neutralize added acid. This works within a limited capacity (add too much acid or base and the buffer will eventually be overwhelmed), but within that range, pH stays relatively stable.


Question 5: In a galvanic (voltaic) cell, where does oxidation occur, and what is that electrode called?

  1. Oxidation occurs at the cathode
  2. Oxidation occurs at the anode
  3. Oxidation occurs equally at both electrodes
  4. Oxidation does not occur in a galvanic cell

Correct Answer: B. Oxidation occurs at the anode

Explanation: In any electrochemical cell, oxidation (loss of electrons) always occurs at the anode, and reduction (gain of electrons) always occurs at the cathode. That rule holds for both galvanic and electrolytic cells. What differs between the two cell types is the sign of each electrode and whether the reaction is spontaneous (galvanic) or driven by an external power source (electrolytic).


More AP Chemistry Study Resources

Looking for a study guide to fill a couple gaps, or just want a full length practice exam? A few resources worth checking out below. If you do find these recommendations useful, please shop through the affiliate links to help support this site.

Barron's AP Chemistry Premium Study Guide

A thorough content review with a heavy emphasis on the calculation-based problem sets this exam is known for.


Princeton Review Cracking the AP Chemistry Exam

Good at breaking multi-step free-response problems into manageable pieces, which is exactly the skill this exam rewards.


AP Chemistry Equations and Constants Practice Sheets

Practicing with the same reference tables you'll get on test day builds real speed with the formulas before the clock is running.


Plenty of other resources exist – just do a quick internet search – but these are a good place to start.